Contaminant Chemistry Overview
- Functional Groups,
Chemical Properties, and Hazards
Transport Mechanisms
-
Advection
- Mechanical Dispersion
- Diffusion (Chemical Dispersion)
Contaminant
Solubility Rules
- Molecular Geometry
- Effective Solubility
3-
and 4-Phase Equilibrium Partitioning
-
Adsorption and Absorption
- Applications of Kd, Koc, foc, Kow,
and KH
- NAPL
and the One Percent Rule
- Molar Fraction Calculations-
Contaminant Mass Fraction Calculation
- Residual
Saturation Calculation
Groundwater
Transport
- Hydrogeology Review
-
Three Point Problem
- Groundwater Velocity Calculations
-
Retardation and Solute Velocity Calculations
Nonaqueous
Phase Liquid (NAPL) Transport
- Capillary Fringe
Interactions and Smear Zones
- Estimating LNAPL
Thickness from Well Free Product
- Estimating
DNAPL Critical Height |
Vapor
Transport
- Vapor
Pressure, Solubility, Molecular Weight, and Vapor Density
- Contact
Surface and Henry's Law Partitioning
- Vapor Diffusion and Air-Filled Porosity
Natural
Attenuation
-
Overview of Natural Attenuation Processes
- Biodegradation Pathways
for Common Contaminants
Focus on Hydrocarbon
Contamination
- Gasoline and Diesel Chemistry
-
BTEX, Oxygenates, Additives, and Other Potential Concerns
- Ethanol Cosolvation and Plume Elongation
-
Geochemical Indicators of Natural Attenuation
- Plume Behavior and Zones
Focus
on Chlorinated Hydrocarbon Contamination
-
Chlorinated Solvent Chemistry
-
Type I, II, and III Plume Behavior
- Reductive
Dechlorination and Cometabolization
- Geochemical
Indicators of Natural Attenuation
Focus
on Metal Contaminants
- Mobility, pH, and Amphoterism
- Dissolved
and Particulate Forms
- Cation/Anion Exchange and Variably Charged Soils
-
Complexation, Chelation, and Ligands
-
Hydrated Metals as Acids |